Kinetic Study of Copper Retention by Kaolin Using a System of Supports Designed in 3D
A. Macías-García （ Department of Mechanical, Energetic and Materials Engineering. School of Industrial Engineering. University of Extremadura. Avda. de Elvas, s/n, 06006, Badajoz. Spain ）
J.E. Calderón-Rios （ Department of Mechanical, Energetic and Materials Engineering. School of Industrial Engineering. University of Extremadura. Avda. de Elvas, s/n, 06006, Badajoz. Spain ）
M.A. Díaz-Díez （ Department of Mechanical, Energetic and Materials Engineering. School of Industrial Engineering. University of Extremadura. Avda. de Elvas, s/n, 06006, Badajoz. Spain ）
D. Torrejón-Martín （ Department of Mechanical, Energetic and Materials Engineering. School of Industrial Engineering. University of Extremadura. Avda. de Elvas, s/n, 06006, Badajoz. Spain ）
Juan Pablo Carrasco-Amador （ University of Extremadura ）
https://doi.org/10.37155/2717-526X-0201-3Abstract
Kaolin is a clay product of the decomposition of feldspatic rocks; it is a hydrated aluminum silicate whose main component is kaolinite; its formula is 2H2O-Al2O3-2SiO2 and it has a wide application in various industries. In this study copper ions removal of aqueous solutions using kaolin, was investigated. Kaolin sample are texturally and chemically characterized and its electrical conductivity was established, and finally diverse kinetic models were tested to the copper ion retention process. Kinetic adsorption and electroadsorption processes of Cu (II) ions on kaolin are practically identical. The qe values for both adsorption and electroadsorption are of the order of 10.1 mg·g-1 for an equilibration time of 1200 min. This suggests that adsorption procedure is the determining factor. In view of results, we can indicate that kinetic adsorption procedure of Cu (II) ions on kaolin is adjusted to a pseudo second order kinetics. High regression coefficients are reached, greater than those of first order pseudo model, with worths above 0.99. Its explanation comes from the valence forces involved in the adsorption mechanism, due to electrons exchange between Cu (II) ions and the adsorbent. Likewise, correlation between experimental qe values, and the calculated qe, through the kinetic model are good. A more detailed observation through intraparticle diffusion model allows us to distinguish two well defined linear parts, a first one: that would correspond to the transport of ions from the dissolution to the external covering of the absorbent, with a fast ions distribution on the external kaolin covering. And a second part, which symbolize the intraparticular diffusion, as well as Cu (II) union with the kaolin internal active sites.
Keywords
Kaolin; copper; adsorption; kineticFull Text
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Copyright © 2020 A. Macías-García, J.E. Calderón-Rios, M.A. Díaz-Díez, D. Torrejón-Martín, Juan Pablo Carrasco-Amador
Publishing time:2020-06-30
This work is licensed under a Creative Commons Attribution 4.0 International License
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