Principle and Research Status of Circulating Flow Batteries
Olivier Fontaine
Xuanze Wang （ Molecular Electrochemistry for Energy Laboratory, School of Energy Science and Engineering, Vidyasirimedhi Institute of Science and Technology (VISTEC), Rayong 21210, Thailand. ）
Jie Deng （ Institute for Advanced Study, Chengdu University, Chengdu 610106, China. ）
Yachao Zhu （ ICGM, Université de Montpellier, CNRS, Montpellier 34293, France ）
Chalarat Chaemchamrat （ Molecular Electrochemistry for Energy Laboratory, School of Energy Science and Engineering, Vidyasirimedhi Institute of Science and Technology (VISTEC), Rayong 21210, Thailand. ）
https://doi.org/10.37155/2717-526X-0602-1Abstract
Circulating Flow Batteries offer a scalable and efficient solution for energy storage, essential for integrating renewable energy into the grid. This study evaluates various electrolyte compositions, membrane materials, and flow configurations to optimize performance. Key metrics such as energy density, cycle life, and efficiency are analyzed. Experimental results show high energy efficiency and long cycle life, making Circulating Flow Batteries suitable for large-scale applications. The modular design allows easy scaling, and their rapid response capability supports grid stability with intermittent renewable sources. Future research should focus on enhancing materials and reducing costs to fully realize the potential of Circulating Flow Batteries in sustainable energy systems.
Keywords
Circulating Flow Batteries; renewable energy storage; molecular engineering; energy densityFull Text
PDFReferences
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2. Luo, J., et al., Status and Prospects of Organic Redox Flow Batteries toward Sustainable Energy Storage. ACS Energy Letters, 2019. 4(9): p. 2220-2240.
3. Arenas, L.F., C. Ponce de León, and F.C. Walsh, Engineering aspects of the design, construction and performance of modular redox flow batteries for energy storage. Journal of Energy Storage, 2017. 11: p. 119-153.
4. Jin, S., et al., A Water-Miscible Quinone Flow Battery with High Volumetric Capacity and Energy Density. ACS Energy Letters, 2019. 4(6): p. 1342-1348.
5. Bartolozzi, M., Development of redox flow batteries. A historical bibliography. Journal of Power Sources, 1989. 27(3): p. 219-234.
6. Zeng, Y.K., et al., A comparative study of all-vanadium and iron-chromium redox flow batteries for large-scale energy storage. Journal of Power Sources, 2015. 300: p. 438-443.
7. Matsuda, Y., et al., A rechargeable redox battery utilizing ruthenium complexes with non-aqueous organic electrolyte. Journal of Applied Electrochemistry, 1988. 18(6): p. 909-914.
8. Sum, E. and M. Skyllas-Kazacos, A study of the V(II)/V(III) redox couple for redox flow cell applications. Journal of Power Sources, 1985. 15(2): p. 179-190.
9. Rychcik, M. and M. Skyllas-Kazacos, Characteristics of a new all-vanadium redox flow battery. Journal of Power Sources, 1988. 22(1): p. 59-67.
10. Luo, Q., et al., Capacity Decay and Remediation of Nafion-based All-Vanadium Redox Flow Batteries. ChemSusChem, 2013. 6(2): p. 268-274.
11. Roznyatovskaya, N., et al., Detection of capacity imbalance in vanadium electrolyte and its electrochemical regeneration for all-vanadium redox-flow batteries. Journal of Power Sources, 2016. 302: p. 79-83.
12. Whitehead, A.H. and M. Harrer, Investigation of a method to hinder charge imbalance in the vanadium redox flow battery. Journal of Power Sources, 2013. 230: p. 271-276.
13. Li, Z., et al., The indefinite cycle life via a method of mixing and online electrolysis for vanadium redox flow batteries. Journal of Power Sources, 2019. 438: p. 226990.
14. Weber, S., et al., Life Cycle Assessment of a Vanadium Redox Flow Battery. Environmental Science & Technology, 2018. 52(18): p. 10864-10873.
15. Cunha, Á., et al., Vanadium redox flow batteries: a technology review. International Journal of Energy Research, 2015. 39(7): p. 889-918.
16. Rugolo, J. and M.J. Aziz, Electricity storage for intermittent renewable sources. Energy & Environmental Science, 2012. 5(5): p. 7151-7160.
17. Leung, P., et al., Recent developments in organic redox flow batteries: A critical review. Journal of Power Sources, 2017. 360(Supplement C): p. 243-283.
18. Dmello, R., et al., Cost-driven materials selection criteria for redox flow battery electrolytes. Journal of Power Sources, 2016. 330: p. 261-272.
19. Li, B., et al., Ambipolar zinc-polyiodide electrolyte for a high-energy density aqueous redox flow battery. Nature Communications, 2015. 6: p. 6303.
20. Goulet, M.-A., et al., Extending the Lifetime of Organic Flow Batteries via Redox State Management. Journal of the American Chemical Society, 2019. 141(20): p. 8014-8019.
21. Murali, A., et al., Understanding and Mitigating Capacity Fade in Aqueous Organic Redox Flow Batteries. Journal of The Electrochemical Society, 2018. 165(7): p. A1193-A1203.
22. Kwabi, D.G., Y. Ji, and M.J. Aziz, Electrolyte Lifetime in Aqueous Organic Redox Flow Batteries: A Critical Review. Chemical Reviews, 2020. 120(14): p. 6467-6489.
23. Forner-Cuenca, A. and F.R. Brushett, Engineering porous electrodes for next-generation redox flow batteries: recent progress and opportunities. Current Opinion in Electrochemistry, 2019. 18: p. 113-122.
24. Prifti, H., et al., Membranes for Redox Flow Battery Applications. Membranes, 2012. 2(2): p. 275-306.
25. Maurya, S., et al., A review on recent developments of anion exchange membranes for fuel cells and redox flow batteries. RSC Advances, 2015. 5(47): p. 37206-37230.
26. Ding, Y., et al., Molecular engineering of organic electroactive materials for redox flow batteries. Chemical Society Reviews, 2018. 47(1): p. 69-103.
27. Huskinson, B., et al., A metal-free organic-inorganic aqueous flow battery. Nature, 2014. 505(7482): p. 195-8.
28. Yang, B., et al., An Inexpensive Aqueous Flow Battery for Large-Scale Electrical Energy Storage Based on Water-Soluble Organic Redox Couples. Journal of the Electrochemical Society, 2014. 161(9): p. A1371-A1380.
29. Lin, K., et al., Alkaline quinone flow battery. Science, 2015. 349(6255): p. 1529.
30. Hu, B., et al., Long-Cycling Aqueous Organic Redox Flow Battery (AORFB) toward Sustainable and Safe Energy Storage. Journal of the American Chemical Society, 2017. 139(3): p. 1207-1214.
31. Gerhardt, M.R., et al., Anthraquinone Derivatives in Aqueous Flow Batteries. Advanced Energy Materials, 2016: p. n/a-n/a.
32. Kwabi, D.G., et al., Alkaline Quinone Flow Battery with Long Lifetime at pH 12. Joule, 2018. 2(9): p. 1894-1906.
33. Yang, Z., et al., Alkaline Benzoquinone Aqueous Flow Battery for Large-Scale Storage of Electrical Energy. Advanced Energy Materials, 2018. 8(8): p. 1702056.
34. Wu, M., et al., Extremely Stable Anthraquinone Negolytes Synthesized from Common Precursors. Chem, 2020. 6(6): p. 1432-1442.
35. Ji, Y., et al., A Phosphonate-Functionalized Quinone Redox Flow Battery at Near-Neutral pH with Record Capacity Retention Rate. Advanced Energy Materials, 2019. 9(12): p. 1900039.
36. Jiang, H.R., et al., Towards a uniform distribution of zinc in the negative electrode for zinc bromine flow batteries. Applied Energy, 2018. 213: p. 366-374.
37. Kim, D. and J. Jeon, Study on Durability and Stability of an Aqueous Electrolyte Solution for Zinc Bromide Hybrid Flow Batteries. Journal of Physics: Conference Series, 2015. 574: p. 012074.
38. Wu, M.C., et al., Improved electrolyte for zinc-bromine flow batteries. Journal of Power Sources, 2018. 384: p. 232-239.
39. Zhang, J., et al., An all-aqueous redox flow battery with unprecedented energy density. Energy & Environmental Science, 2018.
40. Guo, L., et al., Inhibition of Zinc Dendrites in Zinc-Based Flow Batteries. Frontiers in Chemistry, 2020. 8(557).
41. Janoschka, T., et al., An aqueous, polymer-based redox-flow battery using non-corrosive, safe, and low-cost materials. Nature, 2015. 527: p. 78.
42. Navalpotro, P., et al., A Membrane-Free Redox Flow Battery with Two Immiscible Redox Electrolytes. Angewandte Chemie International Edition: p. n/a-n/a.
43. Navalpotro, P., et al., Exploring the Versatility of Membrane-Free Battery Concept Using Different Combinations of Immiscible Redox Electrolytes. ACS Applied Materials & Interfaces, 2018.
Copyright © 2024 Olivier Fontaine, Xuanze Wang, Jie Deng, Yachao Zhu, Chalarat Chaemchamrat
Publishing time:2024-11-26
This work is licensed under a Creative Commons Attribution 4.0 International License
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