Oxidative Dehydrogenation of Propane over Nanostructured Mesoporous VOx/CexZr1-xO2 Catalysts
Bao Agula
Minglei Sun
Shihang Liang
Yongsheng Bao
Meilin Jia
Feng Xu
Zhong-Yong Yuan （ School of Materials Science and Engineering, Nankai University, Tianjin, China. ）
https://doi.org/10.37155/2717-526X-0402-5Abstract
High-surface-area mesoporous CexZr1-xO2 materials synthesized through a surfactant-assisted approach of nanocrystalline particle assembly are utilized as a promising support for VOx-based catalysts. The catalytic properties of the resultant VOx/CexZr1-xO2 nanocatalysts are evaluated by the oxidative dehydrogenation of propane using a microreactor-GC system. It is indicated that the catalyst particles are on a nanoscale, having a mesoporous structure with uniform pore-size distribution and high surface area. The catalytic behavior of these mesoporous nanostructured VOx/CexZr1-xO2 catalysts for the oxidative dehydrogenation of propane reaction relies on the vanadia loading amount, the calcination temperature, the surface area and the Ce/Zr ratio of the supports, the particle size of active compounds, and the additional contribution to the propylene formation derives from the contribution of the catalytic dehydrogenation of propane under oxygen-lean conditions. The catalyst prepared with 8 wt% vanadia loading on Ce0.2Zr0.8O2 exhibits high and stable catalytic performance in the oxidative dehydrogenation of propane reaction.
Keywords
VOx/CexZr1-xO2 catalysts; Mesoporous materials; Nanostructure; Oxidative dehydrogenation of propane; Vanadia speciesFull Text
PDFReferences
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[21] Gao X, Xin Q and Guo X. Support effects on magnesium-vanadium mixed oxides in the oxidative dehydrogenation of propane. Applied Catalysis A: General, 1994;114(2):197-205. https://doi.org/10.1016/0926-860X(94)80173-8
[22] Watling TC, Deo G, Seshan K, et al. Oxidative dehydrogenation of propane over niobia supported vanadium oxide catalysts. Catalysis Today, 1996;28(1-2):139-145. https://doi.org/10.1016/0920-5861(95)00221-9
[23] Blasco T, Galli A, Nieto JML, et al. Oxidative dehydrogenation of ethane andn-butane on VOx/Al2O3 catalysts. Journal of Catalysis, 1997;169(1):203-211. https://doi.org/10.1006/jcat.1997.1673
[24] Khodakov A, Olthof B, Bell AT, et al. Structure and catalytic properties of supported vanadium oxides: support effects on oxidative dehydrogenation reactions. Journal of Catalysis, 1999;181(2):205-216. https://doi.org/10.1006/jcat.1998.2295
[25] Lemonidou AA, Nalbandian L and Vasalos IA. Oxidative dehydrogenation of propane over vanadium oxide based catalysts: effect of support and alkali promoter. Catalysis Today, 2000;61(1-4):333-341. https://doi.org/10.1016/S0920-5861(00)00393-X
[26] Chen C, Sun M, Hu Z, et al. Nature of active phase of VOx catalysts supported on SiBeta for direct dehydrogenation of propane to propylene. Chinese Journal of Catalysis, 2020;41(2):276-285. https://doi.org/10.1016/S1872-2067(19)63444-3
[27] Reina TR, Ivanova S, Idakiev V, et al. Nanogold mesoporous iron promoted ceria catalysts for total and preferential CO oxidation reactions. Journal of Molecular Catalysis A: Chemical, 2016;414:62-71. https://doi.org/10.1016/j.molcata.2016.01.003
[28] Wang S, Xu X, Xiao P, et al. Cooperative effect between copper species and oxygen vacancy in Ce0.7-xZrxCu0.3O2 catalysts for carbon monoxide oxidation. Frontiers of Chemical Science and Engineering, 2021;15(6):1524-1536. https://doi.org/10.1007/s11705-021-2106-2
[29] Kang M, Song MW and Lee CH. Catalytic carbon monoxide oxidation over CoOx/CeO2 composite catalysts. Applied Catalysis A: General, 2003;251(1):143-156. https://doi.org/10.1016/S0926-860X(03)00324-7
[30] Kim TH, Kang KH, Baek M, et al. Dehydrogenation of propane to propylene with lattice oxygen over CrOy/Al2O3-ZrO2 catalysts. Molecular Catalysis, 2017;433:1-7. https://doi.org/10.1016/j.mcat.2016.12.004
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Copyright © 2023 Bao Agula, Minglei Sun, Shihang Liang, Yongsheng Bao, Meilin Jia, Feng Xu, Zhong-Yong Yuan
Publishing time:2022-09-30
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